Coarsening kinetics of platinum particles on oxide substrates
โ Scribed by T.-M. Ahn; P. Wynblatt; J.K. Tien
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 893 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0001-6160
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โฆ Synopsis
The growth of platinum particles supported on flat alumina substrates, at 900-I loo"C, has been studied for particles ranging in size from 35-120nm. While the observed kinetics of growth were found to be inconsistant with classical (LSW) coarsening models, a reasonable interpretation of the results was obtained from an analysis based on nucleation-inhibited coarsening models. Comparison of the present results with those of earlier studies on smaller particles at lower temperatures has pointed out certain discrepancies which suggest possible directions for improvement of the kinetic models.
R&arm&-Nous avons &die fa croissancc de particules de platine sur des supports plats d'ahtmine, entre 900 et llOOT, pour des particules dont la taiile etait comprise entre 35 et 120nm. Alors que les cinttiques de croissance observees etaient in~mpatibles avec Ies modbles de grossissement classiques (LSW), nous avons pu interpreter raisonnablement les resultats a partir de modeles du grossissement a germination inhibee. La comparaison de nos resultats avec ceux d'ltudes anterieures sur des particuies plus petites a des temperatures inferieures a permis de mettre en evidence des differences. qui suggtrent des directions de recherche possibles pour ameliorer les modeles cinttiques. Zusammenfassung-Das Wachstum von Platinteilchen, die auf flachen Substraten aus Aluminiumoxid bei 900 bis i 100ยฐC liegen, wurde filr TeilchengrH3en von 35 bis 120 nm untersucht. Die beobachtete Wachstumskinetik war mit den kiarsischen Modehen da Vergroberung nicht vertdglich. Dagegen konnten die ~eobachtun~n mit einer Anaiyse auf der Grundla~ eines Modeiles, welches die behinderte Keimbildung berilcksichtigt, hinreichmd gedeutet werden. Aus dem Vergleich dieser Ergebnisse mit solchen friiherer Untersuchungen an kieineren Teilchen bei niedrigeren Temperaturen ergeben sich gewisse Unstimmigkeiten, die mogliche Verbesserungen der kinetischen Modelle nahelegen.
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