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Coadsorption of Cinchona Alkaloids on Supported Palladium: Nonlinear Effects in Asymmetric Hydrogenation and Resistance of Alkaloids Against Hydrogenation

✍ Scribed by W.-R. Huck; T. Mallat; A. Baiker

Book ID
110437514
Publisher
Springer US
Year
2003
Tongue
English
Weight
247 KB
Volume
87
Category
Article
ISSN
1011-372X

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The enantioselective hydrogenation of methyl benzoylformate (MBF) and pyruvaldehyde dimethyl acetal (PA) was investigated under mild experimental conditions on Pt-alumina catalyst modified with MeOCD, MeOCN, MeOQN and MeOQD alkaloid derivatives in acetic acid (AcOH) and in toluene (T). Besides low r