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[(CO)3PPh3FeCNiPr2]⊕, a Novel Stable Carbyneiron Complex Cation

✍ Scribed by Prof. Dr. Ernst Otto Fischer; Dipl.-Chem. Johannes Schneider; Dr. Dietmar Neugebauer


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
257 KB
Volume
23
Category
Article
ISSN
0044-8249

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Neutron Diffraction Study of [K(18-crown
✍ Mary H. Drabnis; Robert Bau; Sax A. Mason; Jeffrey W. Freeman; Richard D. Ernst 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 371 KB

A neutron diffraction analysis was carried out at 120 K on a single crystal of [K(18-crown-6)][(PPh 3 ) 2 ReH 6 Cr(CO) 3 ] • THF in order to locate the hydride ligands. Three of the hydrides are bound terminally to the Re atom while the other three bridge the Re-Cr bond; the bridging hydrides are cl