✦ LIBER ✦
Neutron Diffraction Study of [K(18-crown-6)] [(PPh3)2ReH6Cr(CO)3], a Bimetallic Donor-Acceptor Complex☆
✍ Scribed by Mary H. Drabnis; Robert Bau; Sax A. Mason; Jeffrey W. Freeman; Richard D. Ernst
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 371 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
✦ Synopsis
A neutron diffraction analysis was carried out at 120 K on a single crystal of [K(18-crown-6)][(PPh 3 ) 2 ReH 6 Cr(CO) 3 ] • THF in order to locate the hydride ligands. Three of the hydrides are bound terminally to the Re atom while the other three bridge the Re-Cr bond; the bridging hydrides are closer to the Re atom. This compound can be thought of as a donor-