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CO hydrogenation catalyzed by magnesia-supported osmium derived from Os3(CO)12

✍ Scribed by M. Deeba; J.P. Scott; R. Barth; B.C. Gates

Book ID
113176673
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
578 KB
Volume
71
Category
Article
ISSN
0021-9517

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EPR study of osmium species derived from
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✍ V.A. Shvets; A.L. Tarasov; V.B. Kazansky; H. KnΓΆzinger πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 367 KB

High-valence osmium ions (OS'+ or 0s" ) were stabilized on CeOz and Th02, when the initially impregnated cluster OSCAR was decomposed under oxidizing conditions. This is in contrast to the formation of low-valence ions (OS'+ and 0~~') on Al,03. The presence of osmium on Ce02 and Th02 presumably modi