✦ LIBER ✦

Clustering of NO2− with nitrous acid molecules: Experimental and ab initio MO studies

✍ Scribed by S. Włodek; H. Wincel

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 526 KB
Volume: 106
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85340-3

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✦ Synopsis

The gas-phase equilibria NO;.(HONO), _, + HONO# NO?(HONO), were measured in a high-prrssurc mass spcctromc-1cr between 240 and 350 I(. The following enthalpy channgcs were detcrmined:A.H:,1 = -31. aHy.2 = -21.6 and A$ 3 = -20.3 kcal/mol. These results are discussed in rchtion to the structures of NO;-(HONO),, deduced from ab initio h10 &Icuhtions.

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