Cluster Synthesis by Exchange of Bridge-Forming Carboxylate Ligands
β Scribed by Prof. Dr. Helmut Werner; Peter Thometzek
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 220 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract Six new tetrahedral chalcocyanide cluster compounds, [{Cu~2~(dien)~3~}Re~4~S~4~(CN)~12~] (1), [{Cu(dien)(NH~3~)}~2~Re~4~Se~4~(CN)~12~]Β·2.5H~2~O (2), [{Cu~2~(dien)~3~}Re~4~Q~4~(CN)~12~]Β·__n__H~2~O (Q = Se (3), Te (4)] and [K(H~2~O)~2~]~2~[{Cu~3~(dien)~4~}{Re~4~Q~4~(CN)~12~}~2~]Β·8H~2~O wh
Reaction of [Ti 7 O 4 (OEt) 20 ] with benzoic acid results in the formation of the new cluster [Ti 6 O 4 (OEt) 14 (OOCPh) 2 ] with concomitant rearrangement of the cluster structure. The molecular structure of the new cluster was determined by [a]