✦ LIBER ✦

Rearrangement of a Titanium Alkoxide Cluster upon Substitution of the Alkoxide Groups by Carboxylate Ligands − Synthesis of [Ti6O4(OEt)14(OOCPh)2] from [Ti7O4(OEt)20]

✍ Scribed by Ivan Mijatovic; Guido Kickelbick; Ulrich Schubert

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 213 KB
Volume: 2001
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200108)2001:8<1933::aid-ejic1933>3.0.co;2-5

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✦ Synopsis

Reaction of [Ti 7 O 4 (OEt) 20 ] with benzoic acid results in the formation of the new cluster [Ti 6 O 4 (OEt) 14 (OOCPh) 2 ] with concomitant rearrangement of the cluster structure. The molecular structure of the new cluster was determined by [a]