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Cluster Synthesis. 46. New Mixed-Metal Complexes of the Layer-Segregated Cluster Pt 3 Ru 6 (CO) 21 (μ 3 -H)(μ-H) 3

✍ Scribed by Adams, Richard D.; Barnard, Thomas S.; Cortopassi, Jeffrey E.; Zhang, Lijuan

Book ID
126417856
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
172 KB
Volume
15
Category
Article
ISSN
0276-7333

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📜 SIMILAR VOLUMES

Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 wit
Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 with Phos[phanes — The Synthesis and Structural Characterizations of [Pt(PMe3)3H][Pt3Ru6(CO)21(μ3-H)(μ-H)2] and [Pt3Ru6(CO)20(PPh3)(μ-H)3(μ3H)]
✍ Adams, Richard D. ;Barnard, Thomas S. ;Li, Zhaoyang ;Zhang, Lijuan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 497 KB 👁 1 views

The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d