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Pt 3 Ru 6 Clusters Supported on γ-Al 2 O 3 : Synthesis from Pt 3 Ru 6 (CO) 21 (μ 3 -H)(μ-H) 3 , Structural Characterization, and Catalysis of Ethylene Hydrogenation and n -Butane Hydrogenolysis

✍ Scribed by Chotisuwan, Saowapa; Wittayakun, Jatuporn; Gates, Bruce C.


Book ID
127212210
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
276 KB
Volume
110
Category
Article
ISSN
0022-3654

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Reactions of Pt3Ru6(CO)2(μ3-H)(μ-H)3 wit
✍ Adams, Richard D. ;Barnard, Thomas S. ;Li, Zhaoyang ;Zhang, Lijuan 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 497 KB 👁 1 views

The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d