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Cluster ion beam study of a system with structural isomers: C+n+D2 (n=2–12)

✍ Scribed by Paul A. Hintz; Marianne B. Sowa; Scott L. Anderson

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
553 KB
Volume
177
Category
Article
ISSN
0009-2614

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✦ Synopsis

An ion beam study of the reaction of C.' (n= 2-l 2) with D2 -a system which is known to have reactant structural isomers with very different reactivity -is reported. We give absolute cross sections for the major product channels. By tarying collision energy, we can study the chemistry of both reactive and "unreactive" isomers, and we obtain evidence for multiple stable isomers for cluster sizes where thermal energy kinetics work shows only a single component.

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