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“Click” Synthesis of Nonsymmetrical Bis(1,2,3-triazoles)

✍ Scribed by Aizpurua, Jesus M.; Azcune, Itxaso; Fratila, Raluca M.; Balentova, Eva; Sagartzazu-Aizpurua, Maialen; Miranda, Jose I.

Book ID
118194865
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
388 KB
Volume
12
Category
Article
ISSN
1523-7060

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A Novel ‘Domino-Click Approach’ to Unsym
A Novel ‘Domino-Click Approach’ to Unsymmetrical Bis-1H-1,2,3-triazoles
✍ Abid H. Banday; Bhupinder S. Arora; Mohammed S. Alam; Halmuthur M. Sampath Kumar 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 203 KB

## Abstract Aryl azides **1** were treated with allenylmagnesium bromide (**2**) to generate 1,5‐disubstituted butynyl‐1__H__‐1,2,3‐triazoles **3** in a domino fashion, which upon Cu^I^‐catalyzed 1,3‐dipolar cycloaddition with aryl azides **4** afforded novel bis‐1__H__‐1,2,3‐triazoles **5** in qua