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‘Click’ synthesis of ferrocenyl-, biferrocenyl-, and cobalticenyl-triazolyl-β-cyclodextrins

✍ Scribed by Abdou K. Diallo; Stéphane Menuel; Eric Monflier; Jaime Ruiz; Didier Astruc

Book ID: 104098018
Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 438 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.06.115

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✦ Synopsis

Cu I -catalyzed Huisgen-type dipolar 'click' reactions between azidomethyl-b-cyclodextrin and ethynylferrocene, ethylnylcobaltocenium hexafluorophosphate, and bis(ethynyl)-biferrocene yield the corresponding metallocenyl-1,2,3-triazolyl-b-cyclodextrins. The monometallocenyl 1,2,3-triazolyl-b-cyclodextrins are soluble in water, unlike the biferrocene derivative.

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