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“Click Chemistry” as a Facile Approach to the Synthesis of Polyphosphazene Glycopolymers

✍ Scribed by Xu Huang; Xiao-Jun Huang; An-Guo Yu; Cang Wang; Zheng-Wei Dai; Zhi-Kang Xu

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
359 KB
Volume
212
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

A versatile approach based on click chemistry to synthesize polyphosphazene glycopolymers is presented. The glucose‐substituted polyphosphazene was synthesized by nucleophilic substitution of poly(dichlorophosphazene) with propargylamine and the subsequent azide/alkyne “click” reaction of poly[di(propargylamine)phosphazene] (PDPAP) with azidosugar. The relative proportion of the glucose substituent can be easily controlled over a broad range by varying the amount of azidoglucose used in the azide/alkyne “click” reaction. magnified image

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