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Cleavage Reactions of the Silicon-Silicon Bond of Hexaphenyldisilane

✍ Scribed by Tsai, Tsu Tzu; Lehn, W. L.; Marshall, C. J.


Book ID
126477181
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
304 KB
Volume
31
Category
Article
ISSN
0022-3263

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DimethyZphenyZsiZyZ-and diphenyZmethyZsiZyZ-vinyl carbon bonds are cleaved with ni3uqNF. DesiZyZation of I-phenyZthio-l-trimethyZsiZyZ-lalkenes in the presence of aldehyde moiety gives carbanion adducts. The affinity of fluoride ion for silicon has been well recognized and widely used for the cleava