Cleavage of α,β-Unsaturated Ethers by Diisobutylaluminum Hydride
✍ Scribed by Pino, Piero; Lorenzi, Gian Paolo
- Book ID
- 127189262
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 456 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Nitroalkenes upon treatment with tributyltin hydride in the absence of any catalyst provide a new method for the reduction of 4 B-unsaturated nitrocompounds. Oxidative cleavage of the intermediate stannyl nitronates yielded carbonyl compounds in good yields.
The reaction of a,fMuwsturated aldehydes and ketones with organotin hydrides have been studied intensively by Kuivils and Beumel 1,2 and by Valade and Pereyre 394. Where88 in the first reports on thin subject '9295 selective reduotion of the oarbonyl function (1) wae the only reaction observed, it h