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Cleavage of the furan nucleus in some 2-furylbenzimidazoles

โœ Scribed by A. M. Simonov; F. T. Pozharskii; V. Ts. Bukhaeva; B. A. Tertov


Book ID
112330444
Publisher
Springer US
Year
1970
Tongue
English
Weight
70 KB
Volume
4
Category
Article
ISSN
0009-3122

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Aromatic substitution via organoboranes
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Swrunary: Reaction of 2-lithiofuran or 1-methyl-2-lithiopyrrole with trialkylboranes leads to a borate salt. Subsequent treatment with an appropriate electrophile such as NCS leads to the 2alkylfuran or 1-methyl-2-alkylpyrrole. Electrophilic substitution is among the most important methods known fo