𝔖 Bobbio Scriptorium
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Cleavage of homoallylic alcohols — a novel fragmentation reaction

✍ Scribed by J.S. Yadav; H.P.S. Chawla; Sukh Dev


Book ID
104243703
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
187 KB
Volume
18
Category
Article
ISSN
0040-4039

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Stereochemical requirements for fragment
✍ Robert A. Holton; Robert M. Kennedy 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 243 KB

The fragmentation of 5,6-epoxynorbornan-2-01 and 5,6-epoxynorbornan-2-one have been studied under both acidic and basic conditions. These processes show a clear preference for syn periplanar alignment of breaking bonds. We have recently reported a short and efficient synthesis of the ketol l\_,l emb