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A new reaction: lead(iv) acetate-mediated oxidative fragmentation of homoallylic alcohols

✍ Scribed by Preite, Marcelo D.; Cuellar, Mauricio A.


Book ID
120560125
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
99 KB
Volume
17
Category
Article
ISSN
1359-7345

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The lead (IV) acetate oxidation of cyclo
✍ G.M. Rubottom; R. Marrero; D.S. Krueger; J.L. Schreiner πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 165 KB

The potential use of 1-trimethylsilyloxybicyclo[n.l.O]alkanes, 2, 1 as useful synthetic intermediates has recently been demonstrated. Not only do A serve as precursors to the corresponding cyclopropanols, ,2, 2 but treatment of ,& with acid,3 base,4 or halogen5 results in the