Cleavage and Rearrangement of Ethers with Bases. I. The Reaction of Dibenzyl and Related Ethers with Potassium t-Butoxide 1
โ Scribed by Curtin, David Y.; Leskowitz, Sidney
- Book ID
- 126909406
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 578 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under mom forcing conditions, products of the further hydrolysis of 6 are obtained. Acetolysis in acetic acid gives the benzyl acetates derived from both N-and 0-substitue
In 1961, Woli.nslryl described the conversion of m-bromocamphene to a mixture of 2-and 3-tbutoxy-k,k3imethylbicyclo[3.2.l]oct-2-ene effected by potassium t-butoxide (z-BuOK), and he rationalized the reaction on the basis of a bicyclo[3.2.l]oct-2-yne intermediate (1) that adds