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Clay montmorillonite K10 catalyzed aldol-type reaction of aldehydes with silyl enol ethers in water

โœ Scribed by Teck-Peng Loh; Xu-Ran Li

Book ID
108379426
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
733 KB
Volume
55
Category
Article
ISSN
0040-4020

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On indium(III) chloride-catalyzed aldol
On indium(III) chloride-catalyzed aldol reactions of silyl enol ethers with aldehydes in water
โœ Shลซ Kobayashi; Tsuyoshi Busujima; Satoshi Nagayama ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

Contrary to previous reports, it was found that hydrolysis of silyl enol ethers is superior to the desired condensation in lnCl3-catalyzed aldol reactions of silyl enol ethers with aldehydes in water. The reactions were found to proceed in certain amounts in the presence of a catalytic amount of a L

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ne aldol reaction of siIyl enol ethers with aldehydes is \_wccessfuIly carried out in aqueous media by using a lanthsnide trifluoromethanesulfonate as a catalyst. Water soluble aldehydes are applicable and the catalyst can be recovered andreusedin this reaction.