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Classification of Coordination Polygons and Polyhedra According to Their Mode of Self-Assembly

✍ Scribed by Gerhard F. Swiegers; Tshepo J. Malefetse

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
169 KB
Volume
7
Category
Article
ISSN
0947-6539

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✦ Synopsis

This work extends techniques for the controlled formation of synthetic molecular containers by metalmediated self-assembly. A new classification system based on the self-assembly of such species is proposed. The system: 1) allows a systematic identification of suitable acceptor Β± donor combinations, 2) widens the variety of design possibilities available, 3) allows a ready comparison of the self-assembly of different compounds, 4) reveals useful commonalities between different compounds, 5) aids in the development of novel architectures, and 6) permits identification of systems capable of being switched back-and-forth between architectures.

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