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Molecular Architecture: Coordination as the Motif in the Rational Design and Assembly of Discrete Supramolecular Species—Self-Assembly of Metallacyclic Polygons and Polyhedra

✍ Scribed by Peter J. Stang


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
344 KB
Volume
4
Category
Article
ISSN
0947-6539

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✦ Synopsis


A simple, general systematic strategy has been developed for the rational design by self-assembly of diverse metallacyclic polygons and polyhedra using coordination as the motif. The methodology is illustrated by the self-assembly of various molecular squares, molecular hexagons, and 3 D species, new members of the family of abiotic supramolecular entities. The design features and some advantages of the coordination motif are discussed.