Classical rotational cross sections for H2—HD and HD—HD collisions
✍ Scribed by Alan Gelb; Joseph S. Alper
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 722 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Kcknivc product rotational smte distribwions for if + D2 -HD + D are reported based on the DWA of Suck Salk, and arc shown to agree rellsonablp well with observations. The rotational peak positions are found to have good correlation with computed "semiclassical" angular momentum.
Rate coefficients, in units of 10-~0 cm 3 molecule-~ s-~, for the O(~D) reactions with H2, D 2 and HD at 298 K were determined to be 1.2 \_\_\_ 0.1, 1.1 + 0.1, and 1.2 + 0.1, respectively. The H atom yield in the O(~ D) + HD reaction, relative to that in the O(ID) + H 2 reaction, was measured to be
Complete quantum state distributions for HD (u= 1) and HD(u=2) are obtained by photolyzing HI at 266 nm m the presence of D2 and detecting the nascent HD product via (2+ 1) resonance-enhanced multiphoton ionization (REMPI). Calibration against an effusive oven source ( d 1800 K) yields any necessary