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Classical and quantum hard sphere fluids: Theory and experiment

✍ Scribed by George A Baker Jr.; G Gutiérrez; M de Llano


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
890 KB
Volume
153
Category
Article
ISSN
0003-4916

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✦ Synopsis


A comprehensive picture is presented of what can be reconstructed of the equations of state, at all densities, of both classical and quantum hard sphere fluids (the latter in their ground states) just from the first few coefftcients which are known of the low-density expansions. Extrapolation techniques, mostly Pade and generalizations thereof, are employed and comparisons with computer simulation studies are made wherever these are available.


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✍ Robert Parson 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 319 KB

The effect of resonant intramolecular interactions upon vibrational energy transfer is studied using classical and quantum perturbation theory. It is shown that cancellations attributed previously to quantum interference may equally well be ascribed to a classical mechanism.