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Claisen–Schmidt Condensation Catalyzed by Metal-Organic Frameworks

✍ Scribed by Amarajothi Dhakshinamoorthy; Mercedes Alvaro; Hermenegildo Garcia

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 216 KB
Volume: 352
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200900747

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✦ Synopsis

Abstract

Metal‐organic framework [Fe(BTC) (BTC=1,3,5‐benzenetricarboxylic acid)] is a convenient heterogeneous catalyst for the carbon‐carbon bond forming reaction in toluene between acetophenone and benzaldehyde to give selectively chalcone in high yield. Fe(BTC) appears as a general catalyst able to synthesize selectively different chalcone derivatives bearing various functionalities. Fe(BTC) could be recycled with no significant loss of catalytic efficiency and crystallinity in subsequent runs.

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