Aromatic Claisen Amino Rearrangement in the Series of Fluorinated Anilines. -The influence of the m-substituent on the acid-catalyzed Claisen rearrangement of the N-pentenylanilines (I), (IV), and (VII) is studied. The rearrangement affords a mixture of two o-pentenylanilines in ratios depending on
Claisen aromatic amino rearrangement in the series of fluorinated anilines
β Scribed by A. G. Mustafin; A. R. Gimadieva; I. N. Khalilov; L. V. Spirikhin; A. A. Fatykhov; R. A. Nurushev; I. B. Abdrakhmanov; G. A. Tolstikov
- Book ID
- 105595959
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 228 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1573-9171
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## Abstract __N__β(2βPropynyl)anilines undergo aminoβClaisen rearrangement to a minor extent in the ion source, losing a molecule of HCN under electron impact conditions. However, metastable molecular ions with energies closer to threshold undergo Claisen rearrangement giving rise to more abundant
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