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ChemInform Abstract: Aromatic Claisen Amino Rearrangement in the Series of Fluorinated Anilines.

✍ Scribed by A. G. MUSTAFIN; A. R. GIMADIEVA; I. N. KHALILOV; L. V. SPIRIKHIN; A. A. FATYKHOV; R. A. NURUSHEV; I. B. ABDRAKHMANOV; G. A. TOLSTIKOV

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Aromatic Claisen Amino Rearrangement in the Series of Fluorinated Anilines.

-The influence of the m-substituent on the acid-catalyzed Claisen rearrangement of the N-pentenylanilines (I), (IV), and (VII) is studied. The rearrangement affords a mixture of two o-pentenylanilines in ratios depending on the catalyst used. In the case of the m-trifluoromethyl derivative (IV), one o-pentenylaniline is proposed to undergo a further Cope rearrangement to give the p-pentenylaniline (VI). -(MUSTAFIN, A.

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