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ChemInform Abstract: New Variation of the Aromatic ortho-Claisen Rearrangement: Synthesis of Fused Thiophenes and Pyrroles

✍ Scribed by Krishna C. Majumdar

Publisher: John Wiley and Sons
Year: 2008
Weight: 15 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200852236

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✦ Synopsis

Abstract

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Aromatic Claisen Amino Rearrangement in the Series of Fluorinated Anilines. -The influence of the m-substituent on the acid-catalyzed Claisen rearrangement of the N-pentenylanilines (I), (IV), and (VII) is studied. The rearrangement affords a mixture of two o-pentenylanilines in ratios depending on