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Cl and D nuclear quadrupole coupling in the rotational spectrum of 15N2…DCl and the dynamics of the DCl subunit

✍ Scribed by N.W. Howard; A.C. Legon

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
509 KB
Volume
149
Category
Article
ISSN
0009-2614

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✦ Synopsis

Nuclear quadrupole coupling constants x(C1) and x(D) have been determined together with the rotational constants BO and centrifugal distortion constants DJ for the linear dimers '5N2...D35CI and '5NZ...D'7Cl. The x(C1) of "N,...H(D)CI have been corrected for the electrical effects due to the presence of the N, subunit by using a simple electrostatic model and the corrected values discussed in terms of the H( D)Cl subunit dynamics.

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