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Circular dichroism of the (+)-tris ethylenediamine cobalt (III) ion and the stepwise formation of outer-sphere complexes

โœ Scribed by Larsson, R.; Norman, B.


Book ID
123106698
Publisher
Elsevier Science
Year
1966
Weight
564 KB
Volume
28
Category
Article
ISSN
0022-1902

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Circular dichroism of cobalt(III) comple
โœ Lucjan Dubicki; James Ferguson; Rodney J. Geue; Alan M. Sargeson ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 347 KB

The smgle crystal az~al CD of three Co(ii1) complekes has been measured between 295 and 9 K. For A-Co (sepulchrate) (NO313 the rotatlonal strength R('Tl(E) -lA1) decreases from =l I X lOdo c.g.s. umts at 295 K to ~0 at 80 K. The main features of the smgle crystal CD spectra can be evplamed by a Stai