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Circular Dichroism of Some 2-(Phenylmethyl)pyridine Derivatives

✍ Scribed by Nikolina Berova; Stefan Eojadziev; Nevenka Bresciani-Pahor; Petko M. Ivanova; Biserka Kojić-Prodicć; Rositza Rakovska; ŽIva Ružić-Toroš; Günther Snatzke

Publisher
John Wiley and Sons
Year
1990
Tongue
German
Weight
489 KB
Volume
73
Category
Article
ISSN
0018-019X

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✦ Synopsis

The absolute configuration of the 2-(phenylmethy1)pyridine derivatives 1-9 had been established by X-ray diffraction and chemical correlation. Their CD spectra have been studied in different solvents for the free and protonated forms. It has now been found that, from the sign of the strong CD couplet between 270 and 220 nm, which was observable for all these compounds besides 7 and 9, their absolute configuration can be determined much quicker.

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