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Cinchona-Modified Pt as a Catalyst for Enantioselective Hydrogenation: Criticism of the "Template Model"-A Reply

✍ Scribed by P. Johnston; P.B. Wells


Book ID
112253365
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
337 KB
Volume
156
Category
Article
ISSN
0021-9517

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The enantioselective hydrogenations of ethyl pyruvate (EP), methyl benzoylformate (MBF), ketopantolactone (KPL) and pyruvaldehyde dimethylacetal (PADA) were studied on Pt-alumina catalyst modified by a new modifier namely ␣-isoquinine (␣-IQ) with rigid conformation and for comparison by quinine (Q)