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Cinchona Derivatives as Bifunctional Organocatalysts for the Direct Asymmetric Nitroaldol (Henry) Reaction.

✍ Scribed by Tommaso Marcelli; Richard N. S. van der Haas; Jan H. van Maarseveen; Henk Hiemstra

Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Guanidine-Thiourea Bifunctional Organoca
Guanidine-Thiourea Bifunctional Organocatalyst for the Asymmetric Henry (Nitroaldol) Reaction
✍ Yoshihiro Sohtome; Yuichi Hashimoto; Kazuo Nagasawa πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 112 KB πŸ‘ 2 views

## Abstract Novel bifunctional catalysts having guanidine and thiourea functional groups were developed for the asymmetric Henry (nitroaldol) reaction. Various structural developments of the catalyst revealed that the compound having an octadecyl‐substituted guanidine and thiourea groups linked wit