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CIDNP and triplet-state reactivity of biradicals

✍ Scribed by De Kanter, F. J. J.; Kaptein, R.

Book ID
121369264
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
1018 KB
Volume
104
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Sξ—ΈT0 CIDNP from triplet biradicals. Dete
Sξ—ΈT0 CIDNP from triplet biradicals. Determination of the rate constant for biradical scavenging from magnetic field dependent CIDNP
✍ F.J.J. De Kanter; R. Kaptein πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 English βš– 433 KB

S-To type nuclear spin polarization has been observed in the reaction products of photochemically generated acyl-aIll biradicals in the presence of a scavenger. From the magnetic field dependence of biradical CIDNP the rate constant k of proton abstraction from 2-methyl-2-propanethiol by the alkyl s

Electronic Absorption Spectra of Planar,
Electronic Absorption Spectra of Planar, Conjugated Biradicals in the Lowest Triplet State
✍ Markus Gisin; Jakob Wirz πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 German βš– 717 KB

## Abstract The semiempirical PPP‐SCF‐SCI method has been adapted to even‐electron, open‐shell π‐systems by performing the SCF calculation on the lowest triplet configuration and choosing a limited set of single electronic excitations from the latter for configuration interaction. The basic approxi