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Biradical CIDNP and the dynamics of polymethylene chains

โœ Scribed by de Kanter, F.J.J.; den Hollander, J.A.; Huizer, A.H.; Kaptein, R.

Book ID
121467840
Publisher
Taylor and Francis Group
Year
1977
Tongue
English
Weight
874 KB
Volume
34
Category
Article
ISSN
0026-8976

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S๎—ธT0 CIDNP from triplet biradicals. Dete
S๎—ธT0 CIDNP from triplet biradicals. Determination of the rate constant for biradical scavenging from magnetic field dependent CIDNP
โœ F.J.J. De Kanter; R. Kaptein ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 433 KB

S-To type nuclear spin polarization has been observed in the reaction products of photochemically generated acyl-aIll biradicals in the presence of a scavenger. From the magnetic field dependence of biradical CIDNP the rate constant k of proton abstraction from 2-methyl-2-propanethiol by the alkyl s