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Chromous chloride promoted cyclization of olefinic N-chloro amides. Synthesis of nitrogen heterocycles

โœ Scribed by Lessard, Jean; Cote, Roland; Mackiewicz, Philippe; Furstoss, Roland; Waegell, Bernard


Book ID
127247292
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
929 KB
Volume
43
Category
Article
ISSN
0022-3263

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The chromous chloride promoted addition
โœ J. Lessard; J.M. Paton ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 192 KB

B-chlorocarbamates have previously been prepared from olefins by thermal addition of N,Ndichlorourethane (1,2,3) and by photochemical addition of N-chlorourethane (NCU) (3 a-c, 4). We discovered a convenient way of adding various N-chlorocarbamates to olefins in very good yields using chromous chlor