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Chromium(II)-mediated synthesis of 1,1-bis(trimethylsilyl)alkenes from aldehydes and (Me3Si)2CBr2

โœ Scribed by David M. Hodgson; Paul J. Comina


Book ID
108380232
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
142 KB
Volume
35
Category
Article
ISSN
0040-4039

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1-Trimethylsiloxyalkyl-bis(trimethylsilyl)silanes ( 5), obtained by a base induced isomerization of easily accessable 1-hydroxyalkyl-tris(trimethylsilyl)silanes (1) were hydrolized to give 1-hydroxyalkyl-bis(trimethylsilyl)silanes ( 6), which in presence of sodium hydride underwent a further 1,3-Si,

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