Sequential reaction of the tricarbonyl[(h 6 -phenyl) carbamate]chromium complex 3 with chiral amide bases (see 4 and 5) and electrophiles yielded planar chiral ortho-substituted complexes 6 with up to 70% enantiomeric excess (ee) (Scheme 2, Table 1 and2). The enantiomer purity could be increased to
Chromium-tricarbonyl complexes of phenyl-containing cyclosiloxane
β Scribed by V. S. Kaganovich; M. I. Rybinskaya; A. A. Zhdanov; M. M. Levitskii; B. D. Lavrukhin
- Book ID
- 112447678
- Publisher
- Springer
- Year
- 1987
- Tongue
- English
- Weight
- 312 KB
- Volume
- 36
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
Enantioselective Deprotonation/Electrophile Addition Reactions of Tricarbonyl(phenyl carbamate)chromium Complexes. -Optimized conditions are elaborated for the preparation of chiral ortho-substituted complexes staring from racemic complex (I). The enantiomeric purity of the products can be increase
Chromium tricarbonyl complexes of 3-methoxybenzyl alcohol and related compounds were selectively lithiated at the 4-position in contrast to the corresponding metal free arene compounds. The resulting I-lithio complexes were converted to the I-substituted arene compounds in moderate to excellent yiel