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Tricarbonyl-chromium complexes of benzannelated cycloproparenes

✍ Scribed by Paul Müller; Gérald Bernardinelli; Yvan Jacquier; Alessandra Ricca

Book ID
102858221
Publisher
John Wiley and Sons
Year
1989
Tongue
German
Weight
521 KB
Volume
72
Category
Article
ISSN
0018-019X

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Regioselective lithiation of II-(arene)c
Regioselective lithiation of II-(arene)chromium tricarbonyl complexes
✍ Motokazu Uemura; Naomi Nishikawa; Yuji Hayashi 📂 Article 📅 1980 🏛 Elsevier Science 🌐 French ⚖ 246 KB

Chromium tricarbonyl complexes of 3-methoxybenzyl alcohol and related compounds were selectively lithiated at the 4-position in contrast to the corresponding metal free arene compounds. The resulting I-lithio complexes were converted to the I-substituted arene compounds in moderate to excellent yiel