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Chromatographic Separation and Absolute Configuration of Chiral Methyl 2-Oxobicyclo[3.2.1]octane-6-carboxylate

โœ Scribed by Eugenius Butkus; Ulf Berg; Arvydas Stoncius; Albinas Zilinskas


Book ID
111729696
Publisher
Royal Society of Chemistry
Year
1995
Tongue
English
Weight
209 KB
Volume
5
Category
Article
ISSN
0959-9436

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Each of the chiral 1,2-and 1,3-diols examined was derivatized exclusively to a single diastereomeric acetal by the use of a new axially chiral reagent, 2%-methoxy-1,1%-binaphthalene-8-carbaldehyde (MBC). The absolute configuration of the original 1,2-and 1,3-diols was determined by the NOE correlati