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CH···O and CH···F Links Form the Cage Structure of Dioxane−Trifluoromethane

✍ Scribed by Favero, Laura B.; Giuliano, B. Michela; Melandri, Sonia; Maris, Assimo; Ottaviani, Paolo; Velino, Biagio; Caminati, Walther

Book ID: 127111541
Publisher: American Chemical Society
Year: 2005
Tongue: English
Weight: 76 KB
Volume: 109
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp0527599

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## Abstract Pulse radiolysis techniques were used to measure the gas phase UV absorption spectra of the title peroxy radicals over the range 215–340 nm. By scaling to σ(CH~3~O~2~)~240 nm~ = (4.24 ± 0.27) × 10^−18^, the following absorption cross sections were determined: σ(HO~2~)~240 nm~ = 1.29 ± 0