Chlorotrimethylsilane Catalysed Acylation of Alcohols1
β Scribed by Kumareswaran, R. ;Gupta, Anuradha ;Vankar, Yashwant D.
- Book ID
- 111985398
- Publisher
- Taylor and Francis Group
- Year
- 1997
- Tongue
- English
- Weight
- 169 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0039-7911
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π SIMILAR VOLUMES
General Synthetic Methods. Part 6. Chlorotrimethylsilane-Catalyzed Acylation of Alcohols. -The acylation of a variety of alcohols is effectively catalyzed by chlorotrimethylsilane. This reaction works well with primary, secondary, and allylic alcohols. However, elimination is observed with tertiary
Cobalt(ll) chloride catalysed acylation of anisole with variety of acid chlorides proceeds via an acyl radical to give p-acylated anisoles in good yields.
The use of S-ethyl du 'oo&moate as acyl donor in resolution of secondary alcohols by lipase catalysed transeskfkation, resulted in an efficient displacement of rhe equilibrium towards esterification of the alcohol. A lii (component B) from Can&a antarctica was used 89 the catalyst. On a semi-prepara