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ChemInform Abstract: General Synthetic Methods. Part 6. Chlorotrimethylsilane-Catalyzed Acylation of Alcohols.

✍ Scribed by R. KUMARESWARAN; A. GUPTA; Y. D. VANKAR

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199726087

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✦ Synopsis

General Synthetic Methods. Part 6. Chlorotrimethylsilane-Catalyzed Acylation of Alcohols.

-The acylation of a variety of alcohols is effectively catalyzed by chlorotrimethylsilane. This reaction works well with primary, secondary, and allylic alcohols. However, elimination is observed with tertiary alcohols (VI). All of the optically active alcohols give the corresponding acetates with retention of configurations (e.g. (XVII) and (XIX)). -(KU-

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