Chlorosilicate with the 12CaO.7Al2O3 structure and its relationship to garnet
✍ Scribed by Feng, Q. L. ;Glasser, F. P. ;Howie, R. A. ;Lachowski, E. E.
- Book ID
- 114504265
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 469 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
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## Abstract A novel nano‐porous oxide 12CaO·7Al~2~O~3~ (C12A7) can host a large concentration of interstitial ions, which are present in high concentrations of the order of 10^21^ cm^–3^. We use __ab initio__ calculations and an embedded cluster approach to investigate the effect of the interstitia
We have successfully synthesized a high-purity polycrystalline sample of tetragonal Li 7 La 3 Zr 2 O 12 . Single crystals have been also grown by a flux method. The single-crystal X-ray diffraction analysis verifies that tetragonal Li 7 La 3 Zr 2 O 12 has the garnet-related type structure with a spa