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EPR and Raman investigations into anionic redox chemistry of nanoporous 12CaO·7Al2O3interacting with O2, H2and N2O

✍ Scribed by Monika Ruszak; Stefan Witkowski; Zbigniew Sojka

Book ID
111759921
Publisher
Springer Netherlands
Year
2007
Tongue
English
Weight
521 KB
Volume
33
Category
Article
ISSN
0922-6168

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Electronic structure and spectroscopic p
Electronic structure and spectroscopic properties of interstitial anions in the nanoporous complex oxide 12CaO·7Al2O3
✍ Sushko, P. V. ;Muñoz Ramo, D. ;Shluger, A. L. 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

## Abstract A novel nano‐porous oxide 12CaO·7Al~2~O~3~ (C12A7) can host a large concentration of interstitial ions, which are present in high concentrations of the order of 10^21^ cm^–3^. We use __ab initio__ calculations and an embedded cluster approach to investigate the effect of the interstitia