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Chloropalladated Propargyl Amine: A Highly Efficient Phosphine-Free Catalyst Precursor for the Heck Reaction

✍ Scribed by Consorti, Crestina S.; Zanini, Mara L.; Leal, Sheila; Ebeling, Gunter; Dupont, Jaïrton

Book ID
120809097
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
61 KB
Volume
5
Category
Article
ISSN
1523-7060

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Palladium salts such as Pd(OAc)2 or PdC12(PhCN)2 in the presence of N,N-dimethylglycine (DMG) constitute the simplest and one of the most reactive and selective catalyst systems for the Heck reaction of aryl bromides with olefins known to date.