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On the use of phosphine-free PdCl2(SEt2)2 complex as catalyst precursor for the Heck reaction

✍ Scribed by Adriane S Gruber; Dirce Pozebon; Adriano L Monteiro; Jaı̈rton Dupont

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
81 KB
Volume
42
Category
Article
ISSN
0040-4039

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✍ Danilo Zim; Adriano L. Monteiro; Jaı̈rton Dupont 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 55 KB

PdCl 2 (SEt 2 ) 2 and Pd(OAc) 2 efficiently promote the cross-coupling of aryl bromides and chlorides with arylboronic acids under mild reaction conditions. These methods tolerate a variety of functional groups and represent, from a synthetic point of view, two of the simplest catalyst precursors th