CHLORO ETHERS. II. PREPARATION OF SOME NEW CHLORO ETHERS AND ALKOXYMETHYL ESTERS
β Scribed by Farren, J. W.; Fife, H. R.; Clark, F. E.; Garland, C. E.
- Book ID
- 121689846
- Publisher
- American Chemical Society
- Year
- 1925
- Tongue
- English
- Weight
- 341 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Swnmary: T-butyl 2,2,2-trichloroaceiimi&e (l), reaa?ly prepared by addition of t-butawl to trichloroacetonitrile, is an efficient reagent for the preparation of t-butyl ethers and esters in the presence of a catalytic amount of boron trifhon& etherate. Traditional methods for the preparation of
Sly1 enol ethers of ketones are alkylated with ethyl a-chloro-a-phenylseleno acetate la or with ethyl a-chloro-a-phenylseleno propionate lb, mediated by zinc bromide to give the corresponding a-phenylseleno-y-keto esters 3 in moderate to good yields.