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Chlorine and fluorine atoms adducts with halogenated compounds in the gas phase

✍ Scribed by M. Bilde; J. Sehested; T.E. Møgelberg; O.J. Nielsen; T.J. Wallington


Book ID
117130939
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
107 KB
Volume
28
Category
Article
ISSN
0021-8502

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Rate constants of reactions of chlorine
✍ G. B. Sergeev; V. V. Smirnov; E. V. Porodenko; A. V. Pukhovsky 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 511 KB

The kinetics of liquid phase chlorination of methane in a difluorodichloromethane medium has been studied in a temperature interval of 293-150 K. The value of activation energy found for the hydrogen abstraction stage by a chlorine atom (El) equals 14.2 \* 2.5 kJ/mol, with the processes of chlorine